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Oil dispersant effects remain a mystery

BP sprayed chemicals massively in confronting the gulf spill, but scientists aren't sure how much good — or bad — they did.

September 04, 2010|By Amina Khan, Los Angeles Times

In the wake of the BP oil spill, gaping questions remain about a key tool used during cleanup: the nearly 2 million gallons of chemical dispersants sprayed over the water or onto the gushing wellhead on the seafloor. Do the chemicals help recovery, hinder it — or neither?

Just as dishwashing detergent breaks grease on dirty plates into bits, dispersants help turn a slick of oil into droplets a hair's breadth in size. In droplet form, oil is more easily pulled under by currents, away from birds, otters, seaweed and other marine life near the surface. And because droplets present a greater surface area of oil to water, dispersants should, in theory, permit microbes to chew up oil far faster.

Yet despite more than half a century of dispersant use in oil spill cleanups, the long-term effects that dispersants or dispersant-treated oil have on marine life remain as opaque as a layer of crude.

Scientists say they still don't know whether dispersants truly enable bacteria to digest spilled oil more quickly or whether dispersed oil is safer for marine life than untreated slicks.

They can't say whether it was a help or hindrance that BP decided to spray much of the dispersant not onto the water surface, as is more common, but over oil pouring out of the leaking wellhead 5,000 feet under the sea. Both the high pressure (151 times greater than at the surface) and the oil's temperature (100 degrees Celsius, or 212 degrees Fahrenheit) could have affected dispersant action, either for better or worse.

The size of this spill also made it a standout. An estimated 4.9 million barrels of oil were released, about 19 times the amount in the 1989 Exxon Valdez disaster off Alaska and significantly more than the 1979 Ixtoc spill off the Mexican coast, in which about 3.5 million barrels of crude spilled into the Gulf of Mexico.

"On a scale of the Deepwater Horizon blowout, we don't know for a whole variety of reasons how well dispersants have worked," said Neal Langerman, founder of consulting firm Advanced Chemical Safety.

Bacteria do seem to be digesting the oil in the Gulf of Mexico, according to an Aug. 25 report, but data are mixed on whether dispersants help bacteria along. Mervin Fingas, a retired scientist with the Canadian government, said that of roughly 40 biodegradability studies he surveyed between 1997 and 2008, about 60% said dispersant retarded growth of oil-eating microbes and 15% reported no effect. The remaining 25% noted a positive effect.

But positive findings are open to interpretation. At a 1999 oil spill conference, researchers reported that microbial populations dining on oil treated with the dispersant Corexit 9500 (used by BP in the gulf) grew more than seven times as large as those eating oil dispersed physically, suggesting the bacteria were helping.

Yet a comprehensive 2005 review of dispersants by the National Research Council concluded that the healthy bacterial growth in such studies could easily be due to microbes feeding on dispersant, not oil. "There is no conclusive evidence demonstrating either the enhancement or the inhibition of microbial biodegradation when dispersants are used," the 12 authors wrote.

Some confusion comes from the diversity of dispersant formulas, Fingas said. Some contain chemicals that bacteria prefer to digest. Others block the ability of some microbes to attach to oil droplets and start feeding on the hydrocarbons.

The primary purpose of dispersants is to move oil away from surface-dwelling marine life. In the case of the BP well blowout, because the application was deep under the sea, much of the oil never rose to the surface — which means it went somewhere else, said Robert Diaz, a marine scientist at the College of William and Mary in Williamsburg, Va.

"The dispersants definitely don't make oil disappear. They take it from one area in an ecosystem and put it in another," Diaz said.

The types of dispersants used today are far less noxious than the industrial-strength degreasers used in the past, said Beth McGee, a senior water quality scientist at the Chesapeake Bay Foundation, a nonprofit conservation group in Annapolis, Md., and a coauthor of the 2005 review. Most studies find them nowhere near as harmful as oil, she said.

But the concern is that dispersed oil may do more harm to marine life than oil left alone. And on this point, findings vary widely, in part because lab tests have limitations, said Andrew Nyman, a Louisiana State University professor. In small containers, dispersed oil can't dilute. Studies look at large, quick effects, such as death or deformity. Results depend on the oil type, whether it's fresh, the dispersant, the animal being studied and its life stage.

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